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History[ edit ] In approximately 50 BCE , the Roman philosopher Lucretius proposed that apparently static macroscopic bodies were composed on a small scale of rapidly moving atoms all bouncing off each other. Hydrodynamica front cover In Daniel Bernoulli published Hydrodynamica , which laid the basis for the kinetic theory of gases. In this work, Bernoulli posited the argument, still used to this day, that gases consist of great numbers of molecules moving in all directions, that their impact on a surface causes the gas pressure that we feel, and that what we experience as heat is simply the kinetic energy of their motion. Bernoulli also surmised that temperature was the effect of the kinetic energy of the molecules, and thus correlated with the ideal gas law. In this same work he introduced the concept of mean free path of a particle. Also the logarithmic connection between entropy and probability was first stated by him.

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